A coupling of two random variables \(X\) and \(Y\) is a pair of random variables \((X', Y')\) with a joint distribution such that its marginal distributions are given by those of \(X\) and \(Y\).
Given two random variables \(X\) and \(Y\), we can’t do simple operations on them such as \(X+Y\), unless we know their joint distribution, that is, if they even have one!
If they have a joint distribution, then they live on the same probability space.